| Site Classification | Site | Annual mean | No. Days >50 µg/m3 |
| Kerbside | Camden Roadside | 41.6 | 89 |
| Roadside | Bury Roadside | 39.0 | 65 |
| Roadside | Haringey Roadside | 33.8 | 51 |
| Roadside | Sutton Roadside | 31.2 | 34 |
| Urban Centre | Belfast Centre | 32.5 | 41 |
| Urban Centre | Birmingham Centre | 27.3 | 22 |
| Urban Centre | Bristol Centre | 29.9 | 32 |
| Urban Centre | Cardiff Centre | 33.8 | 40 |
| Urban Centre | Edinburgh Centre | 23.4 | 8 |
| Urban Centre | Glasgow Centre | 27.3 | 18 |
| Urban Centre | Hull Centre | 31.2 | 34 |
| Urban Centre | Leeds Centre | 36.4 | 60 |
| Urban Centre | Leicester Centre | 26.0 | 21 |
| Urban Centre | Liverpool Centre | 32.5 | 36 |
| Urban Centre | London Bloomsbury | 35.1 | 43 |
| Urban Centre | Manchester Piccadilly | 31.2 | 32 |
| Urban Centre | Newcastle Centre | 27.3 | 20 |
| Urban Centre | Nottingham Centre | 29.9 | 31 |
| Urban Centre | Sheffield Centre | 32.5 | 39 |
| Urban Centre | Southampton Centre | 31.2 | 25 |
| Urban Centre | Swansea Centre | 31.2 | 25 |
| Urban Centre | Wolverhampton Centre | 28.6 | 30 |
| Urban Background | Birmingham East | 26.0 | 21 |
| Urban Background | Bolton | 26.0 | 17 |
| Urban Background | Leamington Spa | 24.7 | 13 |
| Urban Background | London Brent | 28.6 | 24 |
| Urban Background | London N Kensington | 31.2 | 34 |
| Urban Background | Port Talbot | 35.1 | 60 |
| Urban Background | Stockport | 27.3 | 17 |
| Urban Background | Thurrock | 28.6 | 28 |
| Urban Industrial | Middlesbrough | 24.7 | 21 |
| Suburban | London Bexley | 29.9 | 33 |
| Suburban | London Eltham | 27.3 | 24 |
| Suburban | London Hillingdon | 32.5 | 50 |
| Rural | Narberth | 18.2 | 1 |
| Rural | Rochester | 26.0 | 18 |
| Remote | Lough Navar | 13.0 | 0 |