National Atmospheric Emissions Inventory

2.4 N2O Emission Estimates

The two major sources of nitrous oxide emissions in the UK are agricultural soils and the manufacture of adipic and nitric acids. Lower levels of emissions arise from combustion processes in the power generation sector and from road transport (Table 2.6 and Figure 2.7).

Table 2.6 UK Emissions of Nitrous Oxide (N2O) by UNECE Category(kt)

  1990 1991 1992 1993 1994 1995 1996 1996%
By UNECE category
Comb. in Energy Prod & Transf. 6.3 6.3 6.0 5.6 5.7 5.9 6.1 3%
Comb. in Comm/Inst/Resid/Agri
    Domestic 0.7 0.8 0.7 0.8 0.7 0.5 0.6 0%
    Other 0.3 0.3 0.3 0.3 0.2 0.2 0.2 0%
Combustion in Industry 1.6 1.6 1.7 1.5 1.4 1.3 1.1 1%
Production Processes 95.3 89.1 72.0 61.3 72.6 66.1 70.3 37%
Extr./Distrib. of Fossil Fuels NE NE NE NE NE NE NE  
Solvent Use 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0%
Road Transport 3.2 3.3 3.7 4.9 6.3 7.7 9.2 5%
Other Transp & Mach.
    Off-Road 2.2 2.3 2.3 2.2 2.2 2.1 2.2 1%
    Other 1.2 1.2 1.2 1.1 1.1 1.1 1.1 1%
Waste Treatment & Disp. 0.4 0.4 0.3 0.3 0.3 0.3 0.2  
Agricult/Forest/Land Use Change
    Animal Wastes 5.2 5.2 5.0 5.0 5.1 5.0 5.1 3%
    Non Livestock Agriculture 98.6 98.1 92.3 90.6 92.6 93.0 93.2 49%
Nature 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0%
Total 215.0 208.6 185.5 173.6 188.1 183.3 189.3 100%

1     UK emissions reported in IPCC format (Salway, 1998) differ slightly due to the different source categories used.
2     Railways, shipping, naval vessels, military aircraft
NE   Not estimated

Figure 2.7 Time Series of N2O Emissions

2.4.1 Agriculture

The calculation of emissions from agricultural soils and animal wastes have been considerably extended in the 1996 inventory using the Revised 1996 IPCC Guidelines (IPCC, 1997) and now considers all the following sources:


Further details of the methodology are given in Appendices 1 and 2.

The emissions from agricultural soils currently account for around 49% of total UK emissions. The most significant sources are fertiliser application and leaching at 26 and 27 kt N2O respectively.

2.4.2 Production processes

Nitrous oxide emissions from adipic acid manufacture (a feedstock for nylon ) and nitric acid manufacture comprise 37% of the total in 1996. The extent of the emission depends on the production of these acids, hence the time series reflects production levels. The UK manufacturer has recently commissioned an abatement unit that should reduce emissions by at least 95%.

2.4.3 Power generation

The contribution from public power generation has been relatively constant between 1990 and 1996 in spite of the trend away from coal towards natural gas combustion.

2.4.4 Road transport

Emissions from road transport are increasing as a result of the increasing numbers of petrol driven cars fitted with three way catalytic converters, since the converters produce significantly larger emissions of nitrous oxide. Between 1990 and 1996, the proportion of the vehicle kilometers with converters has increased from <1% to 33% and emissions have increased by a factor of 2.9 (Figure 2.8). The contribution of road transport to the total is minor but it is important because it is steadily growing in contrast to the other sectors which are declining.

Figure 2.8 The growth in number of cars with catalytic converters